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ChemInform Abstract: Synthesis and Structures of Polysilacage Compounds Containing a Silicon—Silicon Inter-element Linkage

✍ Scribed by Masaki Shimizu; Tamejiro Hiyama; Toshiaki Matsubara; Tokio Yamabe

Publisher
John Wiley and Sons
Year
2001
Weight
24 KB
Volume
32
Category
Article
ISSN
0931-7597

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Stereocontrol in Organic Synthesis Using Silicon-Containing Compounds. A Formal Synthesis of (±)-Thienamycin. -The precursor (IX) of the title antibiotic is prepared from aldol product (Ib), which has a silyl group in the side chain as hydroxy surrogate. The trans disposed substituents at the azeti