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ChemInform Abstract: Stereochemical Control in Organic Synthesis Using Silicon-Containing Compounds

✍ Scribed by I. FLEMING; A. BARBERO; D. WALTER

Publisher
John Wiley and Sons
Year
2010
Weight
23 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereocontrol in Organic Synthesis Using Silicon-Containing Compounds. A Formal Synthesis of (.+-.)-Thienamycin.
✍ I. FLEMING; J. D. KILBURN πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 35 KB πŸ‘ 2 views

Stereocontrol in Organic Synthesis Using Silicon-Containing Compounds. A Formal Synthesis of (Β±)-Thienamycin. -The precursor (IX) of the title antibiotic is prepared from aldol product (Ib), which has a silyl group in the side chain as hydroxy surrogate. The trans disposed substituents at the azeti