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ChemInform Abstract: Synthesis and Structure of New Copper and Silver Complexes (M(PPh3)nX) and Organostannyl Derivatives R3SnX with Pseudochalcogeno-Modified Acyl Anions (X: (NOC(CN)2), (NO2NCN), (N(C(CN)2)2), (NO2C(CN)2), (C(CN) (C(CN)2)2))

✍ Scribed by C. TRETNER; L. JAEGER; J. KOZISEK; M. HVASTIJOVA; K. SUENKEL

Book ID: 112033480
Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 27
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199625287

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## Abstract The first argentate salt of carborane anion, [{(CH~3~CN)~4~Ag~3~}{Ag(CB~11~I~5~Br~6~)~2~}]~__n__~, was prepared from K~2~[CB~11~I~5~Br~6~] and AgNO~3~ followed by recrystallization from acetonitrile. Single‐crystal X‐ray analyses indicate that the CB~11~I~5~Br~6~^2−^ dianion has a signi