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ChemInform Abstract: Synthesis and Structure of an Unprecedented High-Symmetry [Fe4S4Cl4] Cubane-Type Unit in Supramolecular [K4(FeCl4) (C12H24O6)4] [Fe4S4Cl4].

✍ Scribed by Johannes B. Willems; Martin Koeckerling


Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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The structure of 1 is built up from FeMo 12 (H 2 PO 4 ) 6 (PO 4 ) 2 (OH) 6 O 4؊ 24 cluster anions connected to each other via hydrogen bonds. The arrangement of clusters is such that each cluster is surrounded by six equivalent anions resulting in three-dimensional cavities. The charge balancing cat