ChemInform Abstract: Synthesis and Structure of an Unprecedented High-Symmetry [Fe4S4Cl4] Cubane-Type Unit in Supramolecular [K4(FeCl4) (C12H24O6)4] [Fe4S4Cl4].
β Scribed by Johannes B. Willems; Martin Koeckerling
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
The structure of 1 is built up from FeMo 12 (H 2 PO 4 ) 6 (PO 4 ) 2 (OH) 6 O 4Ψ 24 cluster anions connected to each other via hydrogen bonds. The arrangement of clusters is such that each cluster is surrounded by six equivalent anions resulting in three-dimensional cavities. The charge balancing cat