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ChemInform Abstract: Synthesis and Stereochemistry of New Spiranes with 2,5-Cyclohexadiene and 2,3,3a,6,7,7a-Hexahydrobenzofuranone Fragments.

✍ Scribed by G. V. GAVRILOVA; D. P. KRUT'KO; A. A. GAVRILOV; K. P. BUTIN


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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The reaction of 2,6-diarylidenecyclohexanones with hydrazine hydrate in glacial acetic acid resulted in the formation of diastereomers of (E)-2-acetyl-3-aryl-7-arylidene-3,3a,4,5,6,7-hexahydroindazoles. The relative conÐgurations of these diastereomers were unambiguously assigned using 1H and 13C NM