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ChemInform Abstract: Synthesis and Some Transformations of 1-Azido-glycopyranosyl Cyanides - Precursors of Anomeric α-Amino Acids.

✍ Scribed by L. SOMSAK; E. SOS; Z. GYOERGYDEAK; J.-P. PRALY; G. DESCOTES

Book ID
112039931
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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✍ Martin D. Smith; Daniel D. Long; Angeles Martin; Neil Campbell; Yves Bleriot; Ge 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

Tetrahydrofuran α-Azido Esters: Precursors of Anomeric α-Amino Acid Monomers via Radical Bromination. -Highly selective radical bromination of protected carbohydrate C-glycosyl derivatives such as (I) and (IV) gives α-bromo esters which undergo displacement by azide to afford α