ChemInform Abstract: Reductive Transform
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F. A. LAKHVICH; V. A. KOZINETS; YA. M. KATOK; E. V. KOROLEVA
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Article
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2010
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John Wiley and Sons
⚖ 33 KB
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Reductive Transformations of 9-Oxo-11-deoxy-11-methyl-13,15isoxazoloprostanoids. -Reduction of the title prostanoids (I) with K-selectride affords the corresponding 9-hydroxy derivatives (II) in excellent α-selectivity. In contrast, in the presence of sodium borohydride a mixture of α-and β-hydroxy