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ChemInform Abstract: Synthesis and Reductive Transformations of 11-Deoxy-, 11-Deoxy-11- methyl- and 9,11-Ethanoprostanoids with Bicycloheptene Fragments in the ω-Chain.

✍ Scribed by E. V. KOROLEVA; YA. M. KATOK; N. F. BONDAR'; R. V. SKUPSKAYA; F. A. LAKHVICH


Book ID
112041738
Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Reductive Transform
✍ F. A. LAKHVICH; V. A. KOZINETS; YA. M. KATOK; E. V. KOROLEVA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

Reductive Transformations of 9-Oxo-11-deoxy-11-methyl-13,15isoxazoloprostanoids. -Reduction of the title prostanoids (I) with K-selectride affords the corresponding 9-hydroxy derivatives (II) in excellent α-selectivity. In contrast, in the presence of sodium borohydride a mixture of α-and β-hydroxy