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ChemInform Abstract: Synthesis and Reactivity Studies of Model Complexes for Molybdopterin-dependent Enzymes

✍ Scribed by Anders Thapper; Christian Lorber; Jacob Fryxelius; Axel Behrens; Ebbe Nordlander

Publisher: John Wiley and Sons
Year: 2000
Weight: 24 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200038282

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a-Keto acid dependent nonheme iron enzymes1'I catalyze a variety of metabolic reactions involving the functionalization of an unactivated C-H bond, concomitant with the oxidative decarboxylation of the cofactor a-keto acid. A general reaction with substrate (A) proceeds according to Equation (a).