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ChemInform Abstract: Synthesis and Reactivity of Benzothiazol-2-ylcarbonylhydroximoyl Chloride, a Versatile Synthon.

โœ Scribed by A. M. FARAG; K. M. DAWOOD; A. O. ABDELHAMID

Book ID
111699086
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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Synthesis and reactivity of benzothiazol
Synthesis and reactivity of benzothiazol-2-ylcarbonylhydroximoyl chloride, a versatile synthon
โœ Ahmad M. Farag; Kamal M. Dawood; Abdou O. Abdelhamid ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 386 KB

The versatile, hitherto unreported benzothiazol-2-ylcarbonylhydroximoyl chloride (2) was prepared by treatment of the corresponding sulfonium bromide 1 with sodium nitrite and hydrochloric acid in dioxane. Compound 2 reacts with o-aminothiopbenol and with o-phenylenediamine to afford the new ketones