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ChemInform Abstract: Synthesis and Properties of Mechanism-Based Inhibitors and Probes for Inositol Monophosphatase Derived from 6-O-(2′-Hydroxyethyl)-(1R,2R,4R, 6R)-cyclohexane-1,2,4,6-tetraol.

✍ Scribed by J. SCHULZ; J. WILKIE; P. LIGHTFOOT; T. RUTHERFORD; D. GANI

Book ID: 112029685
Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 27
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199613242

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ChemInform Abstract: Synthesis and Inhib

ChemInform Abstract: Synthesis and Inhibitory Properties of (1R,2R,4R,6R)-6-O-(2- Hydroxyethyl)cyclohexane-1,2,4,6-tetraol Derivatives: Mechanistic Probes for the Inositol Monophosphatase Reaction.

✍ J. SCHULZ; D. GANI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

ChemInform Abstract: Synthesis of (+)-(1

ChemInform Abstract: Synthesis of (+)-(1R,2R,4R,6S)-1,6-Epoxy-4-benzyloxycyclohexan-2-ol, a Key Precursor to Inositol Monophosphatase Inhibitors, from (-)-Quinic Acid.

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ChemInform Abstract: Synthesis of (-)-(1

ChemInform Abstract: Synthesis of (-)-(1R,2R,4R,6S)-1,6-Epoxy-4-benzyloxycyclohexan-2-ol, a Key Precursor to Inositol Monophosphatase Inhibitors, from (-)-Quinic Acid.

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Synthesis of (−)-(1R,2R,4R,6S)-1,6-epoxy

Synthesis of (−)-(1R,2R,4R,6S)-1,6-epoxy-4-benzyloxycyclohexan-2-ol, A key precursor to inositol monophosphatase inhibitors, from (−)-quinic acid

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A new and efficient route to (-)-(1R,2R,4R,6S)-l,6-epoxy-4-benzyloxycyclohexan-2-ol is described starting from (-)-quinic acid. The pivotal step involves a La3+-induced reversal of the diastet~eoselectivity for the borchydride reduction of an imm'medi~ cyclnhexan-4-one. (IR,2R,4R,6R)-6-Propyloxycycl

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ChemInform Abstract: Synthesis and Prope

ChemInform Abstract: Synthesis and Properties of 6-Oxo-3,5-dicyano-1,4,5,6-tetrahydrospiro( 4′-R-cyclohexane-1′,4-pyridine)-2-thiols and -selenols.

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