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ChemInform Abstract: Synthesis and Diastereoselective Reactions of N,N-Dibenzylamino Aldehydes and Related Compounds

โœ Scribed by Manfred T. Reetz


Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereoselective Gri
โœ Manfred T. Reetz; Alfred Schmitz ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 35 KB

## Stereoselective Grignard-Type Reactions of Chiral N,N-Dibenzylamino Ketones. -Enantiomerically pure N,N-dibenzylamino ketones (I), derived from chiral ฮฑ-amino acids, react under nonchelating conditions with organometal reagents of type RLi, RMgX, RCeCl 2 . The reactions proceed highly diastere