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ChemInform Abstract: Synthesis and Crystal Structure of M(Nb6Cl15) (M: In, Tl): New Ternary Niobium Halides with Bridged (Nb6Cl18)4- Clusters.

✍ Scribed by H. WOMELSDORF; H.-J. MEYER; A. LACHGAR

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis and Crystal Structure of M(Nb6Cl15) (M: In, Tl): New Ternary Niobium Halides with Bridged (Nb6Cl18)4-Clusters.

-The title compounds are prepared in ΒΏ 90% yield by solid state reaction of M (M: In, Tl), NbCl5 and Nb at 720 β€’ C. Single crystal XRD data are reported for In(Nb6Cl15). The isotypic title compounds crystallize in the orthorhombic space group Pmma with Z = 4. The structure contains (Nb6Cl18)4-clusters connected via terminal chloride ligands to form two sets of chains perpendicular to each other. The chains are linked to a three-dimensional network by other terminal ligands.

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