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ChemInform Abstract: Synthesis and Crystal Structure of Cs(VO2)3(TeO3)2, a New Layered Cesium Vanadium(V) Tellurite.

✍ Scribed by William T. A. Harrison; Jarrod H. N. Buttery


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
31
Category
Article
ISSN
0931-7597

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Synthesis and Crystal Structure of Cs(VO
✍ William T. A. Harrison; Jarrod H. N. Buttery πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 German βš– 116 KB πŸ‘ 2 views

Synthetic Cs(VO 2 ) 3 (TeO 3 ) 2 is built up from infinite sheets of distorted octahedral V V O 6 groups, sharing vertices. These octahedral layers are ΒͺcappedΒΊ by Te atoms (as parts of pyramidal [Te IV O 3 ] 2Β± groups) on both faces of each V/O sheet, with inter-layer, 12-coordinate, Cs + cations p