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ChemInform Abstract: Synthesis and Characterization of New AA′BWO6 Perovskites Exhibiting Simultaneous Ordering of A-Site and B-Site Cations.

✍ Scribed by Graham King; Srinivasa Thimmaiah; Akansha Dwivedi; Patrick M. Woodward

Publisher
John Wiley and Sons
Year
2008
Weight
16 KB
Volume
39
Category
Article
ISSN
0931-7597

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Abstract

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Synthesis, Structure, and Physical Properties of A-Site Ordered Perovskites ACu3Co4O12 (A: Ca and Y). -CaCu3Co4O12, YCu3Co4O12, and their solid solutions Ca1-xYxCu3Co4O12 (x= 0.25, 0.50, 0.75) are synthesized from stoichiometric mixtures of Y2O3, CuO, Co3O4, and Ca2CuO3 in the presence of KClO4 (gol