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ChemInform Abstract: Synthesis and Characterization of Manganese and Cobalt Pyroborates: M2B2O5 (M: Mn, Co).

✍ Scribed by Tetsuya Kawano; Haruhiko Morito; Hisanori Yamane


Publisher
John Wiley and Sons
Year
2010
Weight
17 KB
Volume
41
Category
Article
ISSN
0931-7597

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## Abstract An all‐inorganic complex, [Mn~2~{(VO~3~)~5~}~2~]^6–^ (1), was synthesized, and the structure determination reveals a dinuclear manganese complex coordinated by two cyclic pentavanadate ligands. The cyclic pentavanadate units sandwich the edge‐sharing octahedral dimanganese core through