ChemInform Abstract: Syntheses, Crystal Structures and Spectroscopic Properties of Ag2Nb[P2S6][S2] and KAg2[PS4].
β Scribed by Yuandong Wu; Wolfgang Bensch
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 23 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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for (II) (500 Β°C, 6 d). (I) crystallizes in the orthorhombic space group Pnma with Z = 4. Its structure consists of isolated tetrahedral [TaS4] 3-anions, and Rb + and Ba 2+ cations. The Ba 2+ cations are surrounded by nine S atoms forming distorted tricapped trigonal prisms, whereas the Rb + cations
Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4Β± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space
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