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ChemInform Abstract: Syntheses, Crystal Structures and Si Solubilities of New Layered Carbides Zr2Al4C5 and Zr3Al4C6.

✍ Scribed by Keita Sugiura; Tomoyuki Iwata; Hideto Yoshida; Shinobu Hashimoto; Koichiro Fukuda

Publisher: John Wiley and Sons
Year: 2009
Weight: 17 KB
Volume: 40
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200905016

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## Abstract The monoalkyl complexes [Zr{Me~2~Si(η^5^‐C~5~Me~4~)(η^5^‐C~5~H~3~R)}(R′)Cl] [R = Me, R′ = CH~2~Ph (1); R = Me, R′ = CH~2~SiMe~3~ (2); R = __i__Pr, R′ = CH~2~Ph (3); R = __i__Pr, R′ = CH~2~SiMe~3~ (4); R = SiMe~3~, R′ = CH~2~Ph (5); R = SiMe~3~, R′ = CH~2~SiMe~3~ (6)] have been synthesiz