ChemInform Abstract: Syntheses and Structures of Three f-Element Selenite/Hydroselenite Compounds.
โ Scribed by Wendy L. Burns; James A. Ibers
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 21 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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Synthesis, Structure, and Reactions of Hydride, Borohydride, and Aluminohydride Compounds of the f-Elements -(f-elements: lanthanides and actinides (Th, U); 304 refs.). -(EPHRITIKHINE, M.; Chem.
## Abstract For Abstract see ChemInform Abstract in Full Text.
The title compounds are prepared by reaction of the elements at 850 โข C with fluxes such as BaCl 2 or an eutectic mixture of LiCl/KCl. Single crystal XRD of all three compounds show tetrahedral structures based on CuTe 4 units. BaDyCuTe 3 crystallizes in the orthorhombic space group Cmcm with Z = 4,