ChemInform Abstract: Syntheses and Crystal Structures of the Quaternary Uranium Lanthanide Oxyselenides UYb2O2Se3 and U2Ln2O4Se3 (Ln: Pr, Sm, Gd).
โ Scribed by Adam D. Raw; James A. Ibers
- Book ID
- 112043034
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 28 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
and the R 1 indices are 0.036 and 0.043. The cell of RbSm 2 Ag 3 Se 5 is 4.3223(6), 15.229(2), 17.420(3) A > and the R 1 index is 0.025. All six are closely related three-dimensional tunnel structures. Their anionic frameworks are built from LnSe 6 octahedra and MSe 4 (M โซุโฌ Cu, Ag) tetrahedra. RbLn
## Abstract Single crystals of the title compounds are prepared by evaporation of aqueous solutions of Ln~2~O~3~ (Ln: Ho, Tm, Pr) and H~2~SO~4~ at room temperature.
The compounds Ba4Nd2Cd3Se10 and Ba4Ln2Cd3S10 (Ln โซุโฌ Sm, Gd, Tb) have been synthesized at 1173 K with the use of a BaBr2/ KBr eutectic 6ux. These isostructural compounds crystallize as racemic twins in space group Cmc21 of the orthorhombic system in cells of (Ln, Q, a, b, c (A s ), T (K)