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ChemInform Abstract: Syntheses and Crystal Structures of the closo-Borate M[B8H9] (M: [PPh4]+ and [N(n-Bu4)]+).

✍ Scribed by Florian Schlueter; Eduard Bernhardt


Publisher
John Wiley and Sons
Year
2012
Weight
14 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The [B~8~H~8~]^2‐^ and [B~8~H~9~]^‐^ ions are characterized by NMR spectroscopy, single crystal XRD, and DFT calculations.


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ChemInform Abstract: Syntheses and Cryst
✍ Florian Schlueter; Eduard Bernhardt πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 1 views

Syntheses and Crystal Structures of the closo-Borates M 2 [B 7 H 7 ] and M[B 7 H 8 ] (M: PPh4, PNP, and N(n-Bu4)): The Missing Crystal Structure in the Series [BnHn] 2- (n: 6-12). -The first convenient synthesis of the seven-vertex closo-[B7H7] 2-anion via O2-oxidation of [B9H9] 2-is reported. Proto