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ChemInform Abstract: Substrate Specificity of the Kinetic Resolution of Sulfides by Enantioselective Sulfoxide Formation.

✍ Scribed by M. L. PHILLIPS; J. A. PANETTA

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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## Abstract Enantioselective vanadium‐catalysed oxidation of aryl benzyl sulfides using Bolm’s procedure is accompanied by kinetic resolution in the oxidation of the resulting sulfoxides which enhances the enantiopurities of the sulfoxides recovered (typically >90 % __ee__), albeit with an associat