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ChemInform Abstract: Studies Toward the Synthesis of Vinigrol. First Construction of the Tricyclic Ring System.

โœ Scribed by J.-F. DEVAUX; I. HANNA; J.-Y. LALLEMAND

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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Synthetic Studies Toward the Kempane Diterpenes: Preparation of the Ring System. -Starting with the Diels-Alder reaction of the diene(I) with (II) the adduct (III) is obtained, in which three of the four rings of kempanes are already in place. Transformations via the enone (VII) and stereoselective