𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Studies on the Homodienyl-[1,5]-hydrogen Shift in Vinylaziridines.

✍ Scribed by Jens Aahman; Peter Somfai


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Kinetic study of a homodienyl-[1,5]-hydr
✍ Anita HussΓ©nius; Peter Somfai; David Tanner πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 260 KB

The thermal rearrangement of an N-substituted vinylaziridine to the corresponding (Z)-allylic imine, i.e. a homodienyl-[1,5]-hydrogen shift, was studied at different temperatures in the range 40-90 "C. 'H NMR spectroscopy was used to follow the reaction. Rate constants and activation parameters were

ChemInform Abstract: A Type 1 Intramolec
✍ Aberdeen Allen Jr.; Dana M. Gordon πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB

Intervention of a Thermal [1,5] Hydrogen Shift. -Heating a solution of (Ia) in toluene does not afford the desired intramolecular Diels-Alder adduct, however itaconate (IIa) is isolated. An analogous thermal [1,5] hydrogen shift takes place in three structurally related alkenyl maleates. -(ALLEN JR.