ChemInform Abstract: Structure and Reactivity of Early—Late Heterobimetallic Complexes
✍ Scribed by Nigel Wheatley; Philippe Kalck
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 25 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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The First Chiral Early-Late Heterobimetallic Complex -A Titanium(IV)-Palladium(II) Complex Based on Salenophos. -An improved synthesis of salenophos (X) starting from salicylaldehyde in six steps and 20% overall yield is presented. Treatment with Ti(O-iPr)4 in toluene and then PdI2 in CH2Cl2 affords
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