✦ LIBER ✦
ChemInform Abstract: The First Chiral Early-Late Heterobimetallic Complex - A Titanium(IV)- Palladium(II) Complex Based on Salenophos.
✍ Scribed by A. KLESS; C. LEFEBER; A. SPANNENBERG; R. KEMPE; W. BAUMANN; J. HOLZ; A. BOERNER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
The First Chiral Early-Late Heterobimetallic Complex -A Titanium(IV)-Palladium(II) Complex Based on Salenophos. -An improved synthesis of salenophos (X) starting from salicylaldehyde in six steps and 20% overall yield is presented. Treatment with Ti(O-iPr)4 in toluene and then PdI2 in CH2Cl2 affords the title complex which is investigated in detail.