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ChemInform Abstract: Structure and Dynamics of Lithium-Intercalated SnS2. 6,7Li and 119Sn Solid State NMR.

✍ Scribed by T. PIETRASS; F. TAULELLE; P. LAVELA; J. OLIVIER-FOURCADE; J.- C. JUMAS; S. STEUERNAGEL

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199746010

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✦ Synopsis

1997 structure structure (solids and liquids) D 2000

46 -010

Structure and Dynamics of Lithium-Intercalated SnS 2 . 6,7 Li and 119 Sn Solid State NMR. -Location and dynamics of Li ions inserted into SnS 2 and the effects of Li insertion on the electronic structure of SnS 2 are studied by the title technique. From the results a multistep insertion mechanism is derived with successive occupations of interlayer octahedral and interlayer octahedral + tetrahedral (1:1) sites and final insertion into intralayer sites. The model shows that Li relaxation is not only dominated by its motion but also depends on electron to nuclei fluctuations. -(PIETRASS, T.; TAULELLE,

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