ChemInform Abstract: Structural Frustration and Occupational Disorder: The Rare Earth Metal Polysulfides Tb8S14.8, Dy8S14.9, Ho8S14.9, and Y8S14.8.
β Scribed by Thomas Doert; Christian Graf; Inga G. Vasilyeva; Walter Schnelle
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 13 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
Dark red crystals of the title compounds are prepared by flux reactions of the elements in KBr (1070 K, 10 d) and by metathesis reaction of LnCl~3~ (Ln: TbβHo) and M~2~S~2~ (M: Na, K).
π SIMILAR VOLUMES
## Abstract As revealed by single crystal XRD compounds (II) and (VI) crystallize in the triclinic space group P$\bar 1$ with Z = 2, (IV) in the monoclinic space group P2~1~/m with Z = 4, and (V) in the monoclinic space group P2~1~/n with Z = 4.
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