ChemInform Abstract: Stereospecific Total Synthesis of Somocystinamide A.
β Scribed by Takashi L. Suyama; William H. Gerwick
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 23 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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A Novel, Stereospecific Total Synthesis of (Β±)-Ξ΄9(12)-Capnellene from p-Cresol. -The novel synthesis of racemic capnellene (VI) is based on an inverse electron demand Diels-Alder reaction of a cyclohexadienone derived from (I) with cyclopentadiene (II) and an oxa-di-Ο-methane rearrangement of (IV).