ChemInform Abstract: A Novel, Stereospecific Total Synthesis of (.+-.)-δ9(12)- Capnellene from p-Cresol.

✍ Scribed by V. SINGH; S. PRATHAP; M. PORINCHU

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 32 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199732146

✦ Synopsis

A Novel, Stereospecific Total Synthesis of (±)-δ9(12)-Capnellene from p-Cresol.

-The novel synthesis of racemic capnellene (VI) is based on an inverse electron demand Diels-Alder reaction of a cyclohexadienone derived from (I) with cyclopentadiene (II) and an oxa-di-π-methane rearrangement of (IV). -(SINGH, V.;