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ChemInform Abstract: Stereospecific Palladium-Catalyzed Reactions of Siliranes with Alkynes.

โœ Scribed by W. S. PALMER; K. A. WOERPEL


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a โ€œFull Textโ€ option. The original article is trackable via the โ€œReferencesโ€ option.


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ChemInform Abstract: Synthesis of Silire
โœ W. S. PALMER; K. A. WOERPEL ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 28 KB

Synthesis of Silirenes by Palladium-Catalyzed Transfer of Silylene from Siliranes to Alkynes. -The title reaction produces thermally stable silirenes such as (III) which can be further react with monosubstituted acetylenes to yield the trisubstituted siloles (V). This reactivity suggests an unusual