ChemInform Abstract: Stereoselective Total Synthesis of (.+-.)-Swainsonine Based on endo Mode Cyclization.
β Scribed by C. MUKAI; Y. SUGIMOTO; K. MIYAZAWA; S. YAMAGUCHI; M. HANAOKA
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
β¦ Synopsis
Stereoselective Total Synthesis of (Β±)-Swainsonine Based on endo Mode Cyclization.
-The crucial step in the synthesis of title alkaloid (IX) is the endo mode cyclization of cis epoxide (II) by successive treatment with Co 2 (CO) 8 , Lewis acid, and CAN. The trans-piperidine (III) is formed as major diastereomer with retention of configuration at the propynyl center.
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v