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ChemInform Abstract: One-Pot, New Stereoselective Synthesis of endo-Tropanamine.

✍ Scribed by Marcello Allegretti; Valerio Berdini; M. Candida Cesta; Roberto Curti; Luca Nicolini; Alessandra Topai

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
33
Category
Article
ISSN
0931-7597

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Stereoselective Total Synthesis of (Β±)-Swainsonine Based on endo Mode Cyclization. -The crucial step in the synthesis of title alkaloid (IX) is the endo mode cyclization of cis epoxide (II) by successive treatment with Co 2 (CO) 8 , Lewis acid, and CAN. The trans-piperidine (III) is formed as major