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ChemInform Abstract: Stereoselective Synthesis of syn-Configured α-Allenols by Rhodium-Catalyzed Reaction of Alkynyl Oxiranes with Arylboronic Acids.

✍ Scribed by Tomoya Miura; Masahiko Shimada; Paula de Mendoza; Carl Deutsch; Norbert Krause; Masahiro Murakami

Publisher: John Wiley and Sons
Year: 2010
Weight: 49 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201001074

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## Abstract The stereochemical outcome of the reaction is opposite to that of the corresponding reaction of (I) and (II) using a palladium catalyst which selectively produces (E)‐isomers.