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ChemInform Abstract: Stereoselective Synthesis of Methyl 7-Dihydro-trioxacarcinoside B.

โœ Scribed by Christian M. Koenig; Klaus Harms; Ulrich Koert

Publisher
John Wiley and Sons
Year
2008
Weight
17 KB
Volume
39
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereoselective Syn
ChemInform Abstract: Stereoselective Synthesis of (-)-Metasequoic Acid B.
โœ A. ABAD; C. AGULLO; M. ARNO; A. CANTIN; A. C. CUNAT; B. MESEGUER; R. J. ZARAGOZA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 25 KB ๐Ÿ‘ 1 views

Stereoselective Synthesis of (-)-Metasequoic Acid B. -The synthesis of the title compound (I) is studied starting from (-)-carvone. The key steps are formation of a phenanthrenone system and selective cleavage of the C13-C14 bond leading to the ent-labdane skeleton. -(ABAD, A.; AGULLO, C.;