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ChemInform Abstract: Stereoselective Synthesis of Fluorinated Isoxazolidines and 2,3-Dihydroisoxazoles: A Cycloadditive Route to Enantiomerically Pure Amino Fluoro Alcohols.

✍ Scribed by Luca Bruche; Alberto Arnone; Pierfrancesco Bravo; Walter Panzeri; Cristina Pesenti; Fiorenza Viani

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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Stereoselective Synthesis of Fluorinated
Stereoselective Synthesis of Fluorinated Isoxazolidines and 2,3-Dihydroisoxazoles: A Cycloadditive Route to Enantiomerically Pure Amino Fluoro Alcohols
✍ Luca BruchΓ©; Alberto Arnone; Pierfrancesco Bravo; Walter Panzeri; Cristina Pesen πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 266 KB

20.1 Hz, 1 F, CH 2 F). Οͺ Selected NOEs (CDCl 3 ): {3-H} enhanced (Q, 2 Me), 47.83 (D, C-3), 57.07 (Dd, 3 J C,F Ο­ 5.5 Hz, C-4), 62.10 (T, 2 OCH 2 ), 70.90 (D, C-2), 71.76 (Dd, 2 J C,F Ο­ 19.0 Hz, C-5), 4-H (2%), 5-H (1%), 2-CH 2 (2%), 1Ј-OCH 2 (0.5%) and 1Ј-CH 2 (1%); {4-H} enhanced 3-H (2%), 5-H (2.5