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ChemInform Abstract: Stereoselective Synthesis of Enantiomerically Pure β-Fluoroalkyl γ-Butyrolactones by Sulfoxide-Directed Lactonization.

✍ Scribed by Pierfrancesco Bravo; Alberto Arnone; Paola Bandiera; Luca Bruche; Yuji Ohashi; Taizo Ono; Akiko Sekine; Matteo Zanda

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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Enantioselective Hydrogenation of β-Keto Sulfones with Chiral Ru(II)-Catalysts: Synthesis of Enantiomerically Pure Butenolides and γ-Butyrolactones. -A highly enantioselective synthesis of chiral β-hydroxy sulfones (II), (VII) and (XII) is presented involving a novel ruthenium-catalyzed hydrogenati