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ChemInform Abstract: Stereoselective Synthesis of 2,3-cis-2-Alkyl-5-oxo-3- silyloxycyclopentanecarboxylates Using Dirhodium(II)-Catalyzed Intramolecular C-H Insertion Reaction of 2-Diazo-3-oxo-5- silyloxyalkanoates.

✍ Scribed by T. YAKURA; S. YAMADA; A. UEKI; M. IKEDA


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Dirhodium(II)-Catal
✍ T. YAKURA; S. YAMADA; Y. KUNIMUNE; A. UEKI; M. IKEDA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 39 KB

## Dirhodium(II)-Catalyzed Intramolecular Carbon-Hydrogen Insertion Reaction of Ξ±-Diazo Ketones: Stereoselective Synthesis of 2,3-cis-2-Alkyl-5-oxo-3-silyloxycyclopentanecarboxylates. -In continuation of earlier studies the title reaction leading to cyclopentanones such as (VII) and (VIII) is inv