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ChemInform Abstract: Stereoselective Synthesis of (-)-(1R,2S)-2-Aminocyclobutane-1-carboxylic Acid, a Conformationally Constrained β-Amino Acid.

✍ Scribed by Marta Martin-Vila; Cristina Minguillon; Rosa M. Ortuno

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of (+)-(R)-1-Amino-2,2-difluorocyclopropane-1-carboxylic Acid Through Lipase-Catalyzed Asymmetric Acetylation.
✍ Masayuki Kirihara; Tomofumi Takuwa; Masashi Kawasaki; Hiroko Kakuda; Shun-ichi H 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB

Synthesis of (+)-(R)-1-Amino-2,2-difluorocyclopropane-1-carboxylic Acid Through Lipase-Catalyzed Asymmetric Acetylation. -Hydrochloride (VIII) of the title compound is prepared via the asymmetric acetylation of diol (III) as the key step. Several enzymes and conditions are investigated to obtain th