Stereoselective hydroformylation of methallylic alcohols of types 3 and 4, that employed the substratebound catalyst-directing ortho-diphenylphosphanylbenzoyl (o-DPPB) group, was used as a key step for the construction of bifunctionalized stereotriads, which are central building blocks of polyketide
ChemInform Abstract: Stereoselective Hydroformylation: Key Step for the Assembly of Polypropionate Subunits.
β Scribed by Bernhard Breit; Stephan K. Zahn
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 39 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
The Stereoselective Synthesis of 4-Formyltrinem, a Key Intermediate for Novel Trinems. -Title compound (VIII) is a key intermediate for the preparation of a wide range of trinem derivatives. This is demonstrated by performing some Wittig reactions.