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ChemInform Abstract: Stereocontrolled Formation of Epoxy Peroxide Functionality Appended to a Lactam Ring.

✍ Scribed by Charles M. Marson; Afzal Khan; Rod A. Porter

Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
32
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Functionalization o
ChemInform Abstract: Functionalization of a Ξ²-Lactam Ring via Nucleophilic Displacement of a 4-Vinyloxy Substituent.
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Functionalization of a Ξ²-Lactam Ring via Nucleophilic Displacement of a 4-Vinyloxy Substituent. -Similar to an acyloxy group the 4vinyloxy substituent in Ξ²-lactams (I) and (III) can be displaced by nucleophiles in the presence of a Lewis acid.