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ChemInform Abstract: Stereochemistry and Fate of Hydrogen Atoms in the Diol-Dehydratase-Catalyzed Dehydration of meso-Butane-2,3-diol.

✍ Scribed by P. MANITTO; G. SPERANZA; G. FONTANA; A. GALLI


Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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18 O-Substituted propane-1,2-diols and meso-butane-1,2-diols were synthesized and fed to growing cells of Lactobacillus brevis. Propan-1-ol and butan-2-ol, prepared from such diols through diol-dehydratase-catalyzed dehydration followed by intracellular reduction, were analyzed for their 18 O-conten