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ChemInform Abstract: Solvent Effects on the Steric Course of the Solvolysis of Tertiary Acyclic Derivatives.

✍ Scribed by Paul Mueller; Jean-Claude Rossier

Publisher
John Wiley and Sons
Year
2001
Weight
27 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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Solvent Effects on the Rearrangements of Tertiary Alkynols. -Water effects remarkably iodonium-induced rearrangement of linear alkynols in acetonitrile: While in aqueous solutions Ξ²-iodo-. alpha.,Ξ²-unsaturated ketones, e.g. (II), (IV), and (VI), are the principal reaction products, in dry acetonitr