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ChemInform Abstract: SmI2-Mediated Radical Cyclizations Directed by a C—Si Bond.

✍ Scribed by Hassan Y. Harb; Karl D. Collins; Jose V. Garcia Altur; Sue Bowker; Leonie Campbell; David J. Procter

Publisher
John Wiley and Sons
Year
2011
Weight
39 KB
Volume
42
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Diastereoselective
ChemInform Abstract: Diastereoselective SmI2-Mediated Cascade Radical Cyclizations of Methylenecyclopropane Derivatives — A Synthesis of Paeonilactone B.
✍ R. J. BOFFEY; M. SANTAGOSTINO; W. G. WHITTINGHAM; J. D. KILBURN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 42 KB 👁 1 views

Diastereoselective SmI 2 -Mediated Cascade Radical Cyclizations of Methylenecyclopropane Derivatives -A Synthesis of Paeonilactone B. -Using the title cascade reaction from (VII) to (IX) as key step the natural product paeonilactone B (XIV) is synthesized in an efficient manner. The relative stereoc