β Scribed by E. A. CHERNYSHEV; T. L. KRASNOVA; A. P. SERGEEV; E. S. ABRAMOVA
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1998 organo-silicon compounds, acyclic C derivatives organo-silicon compounds, acyclic C derivatives S 0062
Siloxanes as Precursors of Silanones.
-The pyrolysis of hexamethyldisiloxane (I) and its copyrolysis with trimethylchlorosilane as well as with tetrachlorosilane is studied. It is shown that the disiloxane (I) forms in situ dimethylsilanone which is introduced into the Si-O bond of a further disiloxane molecule affording a mixture of di-and tetrasiloxanes. In the presence of trimethylsilylchloride insertion of the silanone into the Si-Cl bond is also observed. -(CHERNYSHEV, E. A.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The Generation and Capture of Methyl(vinyl)silanone. -The reaction of vinyl(methyl)dichlorosilane with hexamethyldisiloxane in the presence of dimethyl sulfoxide is studied. It is shown that the interaction of vinyl(methyl)dichlorosilane with DMSO generates a vinyl(methyl)silanone which reacts with
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v