## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
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ChemInform Abstract: Silica Sulfuric Acid: A Versatile Reagent for Oxothioacetalization of Carbonyl Compounds and Deprotection of 1,3-Oxathiolanes.
β Scribed by Farhad Shirini; Parisa Sadeghzadeh; Masoumeh Abedini
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 36 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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The title reagent (I) methylates a variety of mono-and diketones such as (II), (IV), (VII), or (IX). Aromatic aldehydes (XI) and (XIII) undergo simple methylation only after activation with AlCl3. Reaction of (I) with terminal acetylenes (XVI) allows the carbonyl-alkynylation of diphenyl ketone (IIa