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ChemInform Abstract: Selenium Dioxide E-Methyl Oxidation of Suitably Protected Geranyl Derivatives — Synthesis of Farnesyl Mimics.

✍ Scribed by Ian J. S. Fairlamb; Julia M. Dickinson; Mathew Pegg


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
32
Category
Article
ISSN
0931-7597

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Selenium dioxide E-methyl oxidation of s
✍ Ian J.S Fairlamb; Julia M Dickinson; Mathew Pegg 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 89 KB

Difunctional allylic terpenes are important synthetic building blocks. Functionalisation of protected geranyl derivatives by SeO 2 provides a convenient route to such compounds. The effect of the geranyl protecting group on the oxidation of the terminal E-methyl group was systematically investigated