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ChemInform Abstract: Selectivity in Rhodium(II)-Catalyzed Rearrangements of Cycloprop-2-ene- 1-carboxylates.

✍ Scribed by P. MUELLER; C. GRAENICHER


Book ID
112022621
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
26
Category
Article
ISSN
0931-7597

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Selectivity in Rhodium(II)-Catalyzed Rea
✍ Paul MΓΌller; Christian GrΓ€nicher πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 German βš– 1020 KB

## Abstract The course of the thermocatalytic rearrangement of cycloprop‐2‐ene‐1‐carboxylates in the presence of dirhodium(II) tetrakis(perfluorobutyrate) ([Rh~2~(pfb)~4~]) was investigated by varying the substituents of the cyclopropene ring. Product composition is markedly influenced by the numbe