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ChemInform Abstract: Selective Isomerization of Prop-2-yn-1-ols into α,β- Unsaturated Aldehydes Catalyzed by Ru(η3-CH2C(Me)CH2)2( Ph2PCH2CH2PPh2).

✍ Scribed by M. PICQUET; C. BRUNEAU; P. H. DIXNEUF

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
28
Category
Article
ISSN
0931-7597

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## Abstract The 16‐e^−^ (η^3^‐allyl)‐ruthenium(II) complex [Ru(η^3^‐2‐C~3~H~4~Me)(CO)(dppf)][SbF~6~] is an efficient catalyst for the regioselective isomerization of terminal propargylic alcohols HCCCR^1^R^2^(OH) into α,β‐unsaturated aldehydes R^1^R^2^CCHCHO or ketones R^3^R^4^CC(R^1^)COMe (if R