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ChemInform Abstract: Samarium-Mediated Mild and Facile Method for the Synthesis of Amides.

โœ Scribed by Feng Shi; Jian Li; Chunju Li; Xueshun Jia

Publisher
John Wiley and Sons
Year
2011
Weight
25 KB
Volume
42
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Mild Method for the
ChemInform Abstract: Mild Method for the Synthesis of Thiazolines from Secondary and Tertiary Amides.
โœ A. B. CHARETTE; P. CHUA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 1 views

Mild Method for the Synthesis of Thiazolines from Secondary and Tertiary Amides. -Base-promoted treatment of amides [cf. (I)] with triflic anhydride generates an iminium or imino triflate which reacts with an aminothiol directly to biologically interesting thiazolines. When optically pure cysteine