Dimethyl-2-oxo-6-octene-1,3-diol has been identified as a male-produced pheromone from the Colorado potato beetle. Its gross structure was deduced from its mass and NMR spectra plus synthesis from geraniol. The absolute configuration was determined to be (S) by syntheses of both enantiomers from (R)
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ChemInform Abstract: (S)-3,7-Dimethyl-2-oxo-6-octene-1,3-diol: An Aggregation Pheromone of the Colorado Potato Beetle, Leptinotarsa decemlineata (Say).
โ Scribed by James E. Oliver; Joseph C. Dickens; Thomas E. Glass
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 26 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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Synthesis of (1S,2R,5R)-2-Ethyl-1,5-dimethyl-6,8-dioxabicyclo(3.2.1) octane, the Aggregation Pheromone of Male Beech Bark Beetles, Taphrorychus bicolor (Col., Scol.). -An enantioselective synthesis of the title compound (V) is described in order to prove the absolute configuration of the natural pr